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Photoinduced Intraensemble Electron Transfer in a Base-Paired Porphyrin-Quinone System. Time-Resolved EPR Spectroscopy

✍ Scribed by Berman, Assia; Izraeli, Elad S.; Levanon, Haim; Wang, Bing; Sessler, Jonathan L.


Book ID
121505556
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
656 KB
Volume
117
Category
Article
ISSN
0002-7863

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Triplet electron transfer is observed in a covalently linked porphyrin-quinone in ethanol at temperatures between 160 and I30 IC. Both, the primary porphyrin triplet state 'P-Q and the radxal pair (+P-Q-)T created by light-induced charge separation, are observed by time-reaclved EPR. The latter is i