Photoinduced hydrogen evolution with cytochrome c3-viologen-ruthenium(II) triad complex and hydrogenase
β Scribed by Noriyuki Asakura; Tomohiro Hiraishi; Toshiaki Kamachi; Ichiro Okura
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 114 KB
- Volume
- 172
- Category
- Article
- ISSN
- 1381-1169
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To construct an artificial photosynthetic system, multi-Zn(II)-mesoporphyrins in peptide dendrimers were equipped as a photosensitizer of photoinduced hydrogen evolution in a fourcomponent system (electron donor, photosensitizer, electron carrier, and catalyst), so that hydrogen was evolved effectiv
A series of water-soluble viologen-linked zinc porphyrins with different methylene chain lengths (n = 3-6) between porphyrin and viologen, ZnP(C n V) 4 , were synthesized and characterized. The intramolecular electron transfer rate constants from the porphyrin moiety of ZnP(C n V) 4 to viologen were