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Photoinduced FeCp Bond Cleavage and Insertion Reactions of Strained Silicon- and Sulphur-Bridged [1]Ferrocenophanes in the Presence of Transition-Metal Carbonyls

✍ Scribed by Nga Sze Ieong; Wing Yan Chan; Alan J. Lough; Mairi F. Haddow; Ian Manners

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 415 KB
Volume: 14
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200700961

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## Abstract The transition metal‐catalyzed ring‐opening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fc = Fe(__η__‐C~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^