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Photoinduced electron-transfer α-deoxygenation of aldonolactones. Efficient synthesis of 2-deoxy-d-arabino-hexono-1,4-lactone

✍ Scribed by Andrea Bordoni; Rosa M. de Lederkremer; Carla Marino

Book ID
108080358
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
173 KB
Volume
341
Category
Article
ISSN
0008-6215

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Synthesis of Protected Hexp-(1 → 4)-β-D-GlcpNAc-(1 → 2)-α-D-Manp-(1 → O)(CH2)7CH3 Sequences (Hex: β-D-Glc, 4-deoxy-4fluoro-β-D-Gal, or 4-deoxy-β-D-Gal) Using a Glc-GlcNPhth Donor, Eventually Fluorinated or Deoxygenated at the Oligosaccharide Level. -The title trisaccharide derivatives are prepared