Photoinduced electron-transfer reactions of ruthenium(II) complexes. 1. Reductive quenching of excited tris(2,2'-bipyridine)ruthenium(2+) by aromatic amines
β Scribed by Kitamura, Noboru; Kim, Haeng Boo; Okano, Sumio; Tazuke, Shigeo
- Book ID
- 121397676
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 934 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0022-3654
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The radical ywld of cvatcd tris( 2.3'.bipyrrdinc)ruthcnrum(li) qucnchcd by scvcral ammcs wasdctcrmincd WIUI P dye laser photolysrs method The yrcld is umly and mdcpcndcnr of the free cncrgy chnngc or the radial rormarron process
To obtain information on the ntedctermirung [actors for photoinduced electron-transfer reactIons. thcrmodynamlc puamcters were dctcrmincd for Ru @py):+-orgarnc quencher-acctonitrdc systems WC round large dtikrence m thermodynamic parameters between systems containing electron donors and acceplors 3s