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Photoinduced Electron Transfer in Platinum(II) Terpyridinyl Acetylide Complexes Connected to a Porphyrin Unit

✍ Scribed by Monnereau, Cyrille; Gomez, Julio; Blart, Errol; Odobel, Fabrice; Wallin, Staffan; Fallberg, Anna; Hammarström, Leif

Book ID
120208518
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
298 KB
Volume
44
Category
Article
ISSN
0020-1669

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## Abstract A rigid and linear bridging ligand containing two 4,5‐diazafluorene chelating units separated by an adamantane spacer (diazf‐a‐diazf) has been synthesized and its dinuclear complexes [(bpy)~2~Ru(diazf‐a‐diazf)Ru(bpy)~2~]^4+^ (Ru^II^ · FAF · Ru^II^), [(bpy)~2~Os(diazf‐a‐diazf)Os(bpy)~2~]