In the context of the finite sink approximation, a parametrization of diffusion-limited electron transfer quenching of 9,10-dicyanoanthracene fluorescence by "rr' and 'n' donors is reported. The effective transfer distance R increases with exergonicity for "rr' donors (as shown by previous authors)
✦ LIBER ✦
Photoinduced Electron Transfer in Multiporphyrinic Interlocked Structures: The Effect of Copper(I) Coordination in the Central Site
✍ Scribed by Lucia Flamigni; Anna Maria Talarico; Jean-Claude Chambron; Valérie Heitz; Myriam Linke; Norifumi Fujita; Jean-Pierre Sauvage
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 297 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0947-6539
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## Abstract Electron‐induced dissociations of gas‐phase ternary copper‐2,2′‐bipyridine complexes of Gly‐Gly‐Gly and Gly‐Gly‐Leu were studied on a time scale ranging from 130 ns to several milliseconds using a combination of charge‐reversal (^+^CR^−^) and electron‐capture‐induced dissociation (ECID)