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Photoinduced Electron Transfer in Bisporphyrin–Diimide Complexes

✍ Scribed by Lucia Flamigni; Martin R. Johnston; Lingamallu Giribabu

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
29 KB
Volume
8
Category
Article
ISSN
0947-6539

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✦ Synopsis

The role of fluoride in the Tamao oxidation of a model dialkoxysilane has been analyzed by computational means. A potential energy surface was calculated consistent with the typical synthetic methods required for the conversion of alkoxysilanes to alcohols; fluoride generates reactive fluorosilicates that undergo rearrangement upon attack by hydroperoxide anions (see scheme).

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