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Photoinduced electron transfer in a porphyrin dyad

✍ Scribed by Gust, Devens; Moore, Thomas A.; Moore, Ana L.; Leggett, Lana; Lin, Su; DeGraziano, Janice M.; Hermant, Roel M.; Nicodem, David; Craig, Peter


Book ID
120339398
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
726 KB
Volume
97
Category
Article
ISSN
0022-3654

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A TTF-linked porphyrin dyad and its zinc complex have been synthesized as novel photosystems with a redox-active pendant. The two chromophores of these dyads are not interactive in the absorption spectra, but the fluorescence of the porphyrin chromophore is dramatically quenched by intramolecular el