Photoinduced electrochromism in monolayer assemblies of ion pair change transfer complexes of 4,4′-bipyridinium ions
✍ Scribed by Toshihiko Nagamura; Kenkichi Sakai; Teiichiro Ogawa
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 356 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0040-6090
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4,4'-bipyridinium ions form ion-pair charge-transfer (CT) complexes with tetrakis[3,5-bis(trifluoromethyl)phenyl]borate anion with a discrete absorption maximum at 420 nm in methanol and at 475 nm in 1,2-dimethoxyethane. These CT complexes in 1,2\_dimethoxyethane at 20°C show broad structureless lum
## Abstract Three metal ion bridged self‐assembled (SA) films of __cis__‐di(thiocyanato)‐bis(2,2′‐bipyridyl‐4,4′‐dicarboxylate) ruthenium were fabricated and characterized by contact angle, UV spectra, cyclic voltammetry and XPS. Their photoinduced electron transfer properties (PETP) were examined.