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Photoinduced decomposition of aqueous formaldehyde in the absence and the presence of CO

✍ Scribed by Hyoung-Ryun Park; Nikola Getoff

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
574 KB
Volume
43
Category
Article
ISSN
1010-6030

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✦ Synopsis

The photoinduced decomposition of aqueous formaldehyde in air-free solutions, some saturated with CO, was investigated. The initial quantum yield of aldehyde decomposition, Qi(-HCHO), strongly depends on the substrate concentration.

The presence of CO in the solution essentially diminishes the aldehyde decomposition because of back reactions. The quantum yields of the final products, glyoxal and carboxylic acids (formic and oxalic), are determined under various experimental conditions. A probable reaction mechanism is presented in accordance with the results.

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