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Photoinduced and thermal reactions of molecular σ radical cations of some branched alkanes in low-temperature matrices: An ESR study

✍ Scribed by Keichi Nunome; Kazumi Toriyama; Machio Iwasaki

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 444 KB
Volume: 105
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80052-4

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✦ Synopsis

The photoinduced and thermal reactions of o radical cations of methyl%ubstltuted propanes and butanes in the condensed phases have been characterized by ESR Photoelunination of CH., giving oletiuuc YT radical cations commonly takes place except for Hz elimination from isobutane radical cations The thermal reactions of methyl-substituted butane radical cations in CFCl2CF# were found to be deprotonation from the CH3 group to give primxy alkyl radicals

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