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Photogeneration and reactions of acyclic carbonyl ylides

✍ Scribed by Lev, I. J.; Ishikawa, K.; Bhacca, N. S.; Griffin, Gary W.


Book ID
126889075
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
420 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract The reaction of a six‐membered sulfonium ylide **5** with aldehydes or ketones afforded the oxirane derivatives **6a–d** as a mixture of cis and trans isomers in excellent yields. In addition, the same reactions, using five‐ or six‐membered cyclic oxosulfonium ylides **7** and **11**, g