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Photofragmentation of CH3ONO at 355 nm. Energy distribution in the no fragment

✍ Scribed by F. Lahmani; C. Lardeux; D. Solgadi

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 573 KB
Volume: 102
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87458-2

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✦ Synopsis

The 355 nm photodissociation of g+wous mctbyl nitrite has been studied by monitoring the nascent NO produet using B tx%o-photon laser-induced fluorescence technique. The nascent vibrational and rotational distributions have been measured: the NO fmgment is produced in four vibrational levels of the Found state (d' = 0. 1.X.3) and the distribution peaks at U" = 1 :a11 these vibrational states are rotationally excited. The NO tr.msLtionnl motion has been ewluated by recording the linewidth of individual rotational lines. The translational energy represents 36% of the aGlsblc energy (Eat, = 11310 cm-11 and the internal energy of the NO fragment is 526% of E,,l_

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