𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photoexcited nitrobenzene for benzylic hydroxylation: the synthesis of 17β-acetoxy-9α-hydroxy-3-methoxy-estra-1,3,5(10)-triene

✍ Scribed by Jacqueline Libman; Elisha Berman

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
128 KB
Volume
18
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

A novel method for benzylic hydroxylation is introduced based on the use of photoexcited nitrobenzene.

Applying this method 178-acetoxy-3-methoxy-estra-1,3,5(10)-triene (I) is

📜 SIMILAR VOLUMES

The Crystal Structure of 3-Methoxy-estra
The Crystal Structure of 3-Methoxy-estra-1,3,5(10)-triene-16α Br,17β OH
✍ Dr. K. Szulzewsky; I. Seidel 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 522 KB

## K. SZULZEWSKY, I. SEIDEL 1nst.itnt far Physikalische Chemie der Akademie der Wissenscheitcn der DDR, Berlin The Crystal Structure of 3-Methoxy-estra-1,3,5( 10) -triene-16a Br,l7@ OH Dedicated to Professor Kate BOLL-DORNBERGER on the occasion of her 70th birthday. The steroid 3-Methoxy-estra-1,

Applications of 2,5-bis(trimethylstannyl
Applications of 2,5-bis(trimethylstannyl)thiophene. Synthesis of 3-methoxy-17α,-(5-iodothien-2-yl)-estra-1,3,5(10)trien-17β-ol
✍ S.-H. Lee; R.N. Hanson; D.E. Seitz 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 117 KB

Monotransmetallation of 2,5\_bis(trimethylstannyl)thiophene followed by the addition of estrone 3-methyl ether and iodine yields 3-methoxy-17&(5-iodothien-2-yl)estra-1,3,5(10)trien-178-01. We have sought to employ bis(trialkylstannyl)ethylenes and -arenes as synthetic inter-