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Photoexcitation of potassium octacyanotungstate(IV) and 2,2′-bipyridyl: kinetics and mechanism

✍ Scribed by Syed Iftikhar Ali; Harpal Kaur

Publisher
Springer
Year
1992
Tongue
English
Weight
264 KB
Volume
17
Category
Article
ISSN
0340-4285

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Photoexcitation of potassium octacyanomo
Photoexcitation of potassium octacyanomolybdate(IV) with 1,10-phenanthroline and 2,2′-bipyridyl: kinetics and mechanism of the reaction in acidic medium
✍ S.I. Ali; Harpal Kaur 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 434 KB

Ahstract The kinetics of thermal reactions of photochemically generated [Mo(CN),(CNH)(H,O)]'with l,lO-phenanthroline and 2,2'-bipyridyl in acidic medium were studied in buffer solutions of pH 4.2-7-O and ionic strength 8.0X 10e2 M at 25 "C. The quantum yield of formation of the photoproduct was calc