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Photoelimination in 2-(dimethylamino)ethyl benzoates

✍ Scribed by J.D. Coyle; D.B. Kingston

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 176 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72633-5

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✦ Synopsis

~Po~shtypa2~~iminatiopl~~~inoarb~ccaparmdskos~~si~ stndiedforketams, &it ocaurs also for aldehydes,oarboxylio aoids,oarboxylata esters aud~0therolasses 0ftxmpoImd.l The reaotiaa for slkylesters ofmtio Carboxylio acids is oflawquantumyield (CO&'), aud It appears2 to involve the rapld formation of ~~~~birPdi~locpabreoLdovntogirepr~ts,butwhiohlarg~rsoerts tot& gmmndstate of the starting esterby areverse bydrogeptrensfer Btep (1).

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