𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photoelectron spectrum of hypofluorous acid, HOF

✍ Scribed by J. Berkowitz; J.L. Dehmer; E.H. Appelman

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
267 KB
Volume
19
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The photoelectron spectrum of HOI: has been obtained with He I resonance radiation. Three bands were observed, which can be intripretcd by analogy.to the diatomic halogens. and to the recently reported CIF. The first two bands can be identified with the out-of-pianc and in-plane components of the n&ike outermost orbital of the diatomic halogens, split by the Cs symmetry of HOF. The fist ionization potential is found to be 12.69 + 0.03 cV, in close agreement with :he photoionization value 12.71 i 0.01 eV

πŸ“œ SIMILAR VOLUMES

Photoelectron Spectrum of Tetrazene
Photoelectron Spectrum of Tetrazene
✍ Dr. JΓΌrgen Kroner; Prof. Dr. Nils Wiberg; Dipl.-Chem. Heiner Bayer πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 219 KB
Photoelectron Spectrum of Cyclobutane
Photoelectron Spectrum of Cyclobutane
✍ Dipl.-Ing. Chem. Peter Bischof; Dr. Edwin Haselbach; Prof. Dr. Edgar Heilbronner πŸ“‚ Article πŸ“… 1970 πŸ› John Wiley and Sons 🌐 English βš– 227 KB
Photoelectron Spectrum of HNSO
Photoelectron Spectrum of HNSO
✍ Dr. Bahman Solouki; Dr. Pavel Rosmus; Prof. Dr. Hans Bock πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

The hatched bands of "sulfine" can be deduced by comparison of the spectra (b) and (c). Their assignment follows from an ab initio SCF calculation ['1 and by comparison with SSO and OSO[51; it is supported by the resolved vibrational fine structures in the first three bands and by the change in the