To aidin inteqreting fhe experimental ionizati& potekials CNDO/Z calculatiox~~ gere cassied out asuming that-the ion had the. same geometry as the paren/ free radical. These caIcuI.atio~~ .&owed that theeIectron confiition for ClO, is . ..G b:a: pi: and for ClO; is . ..a. b: 4 with the lowest unoccu
Photoelectron spectrum of chlorine monofluoride
โ Scribed by C.P. Anderson; G. Mamantov; W.E. Bull; F.A. Grimm; J.C. Carver; T.A. Carlson
- Book ID
- 103009166
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 282 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The photoelectron spectrum of CLF was taken with the helium I (21.22 eV) resonance line. Adiabatic ionization potentiais were obtained and assignments made to the three observed bands. Spin-orbit splitting in the first band was found to be in good agreement with theory.
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The rotational spectrum of the pre-reactive complex thiirane-ClF was detected with a fast-mixing nozzle in an FF microwave spectrometer. Rotational constants, centrifugal distortion constants, Cl-nuclear quadrupole and spin-rotation coupling constants were determined for the isotopomers (CH2)2S '''