The electronic structure of Ca@Cso in the gas phase was probed by ultraviolet photoelectron spectroscopy (UPS) ofCa@CG. The electron affinity of Ca@C, was found to be 3.0 eV. The spectrum suggests that Ca donates its two 4s electrons to the Cm t,. LUMO. Ab initio self-consistent field Hartree-Fock c
Photoelectron spectroscopy and electronic structure of Ca@C60
β Scribed by Lai-Sheng Wang; J. M. Alford; Y. Chai; M. Diener; R. E. Smalley
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 364 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1434-6060
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Use of variable photon energy with polarization available from synchrotron radiation has revolutionized the use of photoelectron spectroscopy (PES) in the study of transition metal complexes. The intensity dependence of PES peaks allows their definite assignment, a quantitation of the covalent mixin
The electronic structure and spectroscopy of C~-o is examined using the intermediate neglect of differential overlap (INDO) model. The ground state of the ion distorts from Ih symmetry to either Dsd, D3d or D2h symmetry. The present study reveals that the Dsd structure is the equilibrium structure w