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Photoelectron spectroscopic studies of the adsorption of CO and CO2 on nickel, platinum and copper

โœ Scribed by P.R. Norton; R.L. Tapping

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
578 KB
Volume
38
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The adsorption ofC0 and CO, on platinum. nickel and copper W;IS studied by X-ray and UV photoelectron spectroscopy. The results indicate that CO, is physisorbcd on p!atinum and copper and 1b:it the bonding: of CO on all tbrce metals involves the metal d-electrons and particularly the 5a lcvcl of CO. It is sqgestcd tbnt tbc cwri;y rcquircd to promote ;1 copper d-electron to an unfilled Icvel above :1x Fermi energy is rcsponsiblc for the sinall heal of adsorption of CO on copper.

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