Activation of a CarbonโOxygen Bond of Be
โ
Xiao Zhang; Eric J. Watson; Conor A. Dullaghan; Sergiu M. Gorun; Dwight A. Sweig
๐
Article
๐
1999
๐
John Wiley and Sons
๐
English
โ 98 KB
๐ 2 views
Stable unsaturated heterocycles such as benzofuran are difficult to remove from petroleum by conventional catalytic hydrotreating. However, in a model system, coordination of Mn(CO)(3)(+) to the aromatic ring of benzofuran activates the C-O bond towards insertion of [Pt(PPh(3))(2)] [Eq. (1)]. The in