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Photoelectron Spectra of Vicinal Tricarbonyls

✍ Scribed by Peter Bischof; Rolf Gleiter; Peter Hofmann

Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
611 KB
Volume
58
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The He I photoelectron spectra of tetramethylcyclopentane‐1,2,3‐trione 1, 4,4,6,6‐tetramethylcyclohexane‐1,2,3‐trione 2, bicyclo[1.2.3]octane‐2,3,4‐trione 3, bicyclo[2.2.3]nonane‐2,3,4‐trione 4 and anhydrous ninhydrine 5 are presented. The assignment of the first two bands is discussed using semiempirical calculations together with a qualitative band shape analysis. It is shown that the first two bands in 1 to 4 are due to the ionization of an electron from lone pair combinations of the 2__p__‐oxygen orbitals.

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