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Photoelectron spectra of group V compounds. The elements: Sb4

✍ Scribed by S. Elbel; J. Kudnig; M. Grodzicki; H.J. Lempka

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
486 KB
Volume
109
Category
Article
ISSN
0009-2614

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✦ Synopsis

The flick-tejllpertlture He I phoroclecrron (PE) spectrum ofgweo~~s Sba is presented and assigned on the basis of tfw kno~~n PI3 ionization cnergics of Asa and Pa and from SCC Sa ei~eavalucs and eigcnvcctors. Implications for rhe PE spec-1r3 <>I' rehted antimony compounds XC discuwd.

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The 3d levels ofgascous Sb., have been measured by X-ray photoelectron spectroscopy. Bindmg cnetglcsof534.6 5 0.2 eV (3dj,z) and 513.9 f 0.2 cV (3d,,:) hne been obuined. The boding cnerpes m Sbq are z-1.7 eV lower than the afomlc values, computed usm\_e Dcscbux's DKK-rock program. and = 1.8 cV highe