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Photoelectron, infrared, and theoretical study of 1-aza-5-boratricyclo[3.3.3.01,5]undecane and related compounds

✍ Scribed by Lee, Keui Jen; Livant, Peter D.; McKee, Michael L.; Worley, S. D.


Book ID
121494410
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
751 KB
Volume
107
Category
Article
ISSN
0002-7863

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The 'H, I3C and =Si nuclear magnetic resonance spectra of the parent compound and twelve derivatives of 2,8,9-trioxa-5-aza-l-silatri~yclo[3.3.3.O~~~]undecane (silatrane) are discussed. Effective Taft polarity constants for the silatrane snbstituents are proposed. An equation is developed to correlat