The vibrational and rotational stotc distributions as well as the uansbtional energy have been measured fcr the nascent NO fra=nent afrcr photodissociation of dimcthylniuosamine at 363.5 nm. Four differat vibrational smtes (u" = O-3) and rornrion~l transitions with qunnrum numbzrs up IOJ' = 50 were
Photodissociation of diphenyldiazomethane and energy relaxation in the diphenylcarbene fragment
β Scribed by C. Dupuy; G.M. Korenowski; M. McAuliffe; W.M. Hetherington III; K.B. Eisenthal
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 287 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
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The vacuum UV photodissociation of BrCN has been investigated at pressures in the range O-500 mtorr. Analysis of the CN(B + X) fluorescence reveals parallel fozmatlon of vibrationally excited CN in both the A211 and B \*Z+ states. Coilisionaily mduced intersystcm crossing modifies the observed vibra
Auger and core electron spectra were measured for several germanium compounds in the g;~s phue. The L2M45M45 and L3M4sM4s Auger spectra of GeH4 were deconvolutcd to determine the ener@cs of the individual component peaks. The molecular relaxation energy of the GeH4 Md5 shell was taken to be the aver