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Photodissociation of ClONO 2 : 2. Time-Resolved Absorption Studies of Product Quantum Yields

✍ Scribed by Yokelson, R. J.; Burkholder, James B.; Fox, R. W.; Ravishankara, A. R.

Book ID
127272473
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
222 KB
Volume
101
Category
Article
ISSN
1089-5639

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Cblorme nitrate, CIONO,. was photolyzcd at 249 nm by a 10 ns pulse from an cwmcr laser, and the prrmsry product NO3 was followed by tunable dye-hscr absorpuon at 662 nm. With AI or Ar plusCH4 as cmncr gases bctwccn 20 and 100 Torr, the primary quantum ylcld for NO3 was 0 55 (-0.1 IO +0.3).