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Photodissociation of Arn−mN+2m clusters (n=2 or 3, m=0−n)

✍ Scribed by Thomas F. Magnera; Josef Michl

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
718 KB
Volume
192
Category
Article
ISSN
0009-2614

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✦ Synopsis

Laser-induced photodissociation cross sections of Ar: , ArN:, N4+, Ar: , Ar,N$ , ArN: , and N6+, obtained by sputtering of solid argon-nitrogen mixtures, have been measured in the 270-650 nm range. All the spectra exhibit a band in the UV (305-335 nm) and those of the trimeric ions, except for N :, also have a band in the visible (465-525 nm). The photodissociation products depend on the choice of wavelength in a readily rationalized fashion.

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