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Photodehydrocyclizations in stilbene-like compounds. X. Rearrangements in the photocyclization of 4,5-diphenyltriphenylene and 4,5-diphenylphenanthrene

✍ Scribed by Tinnemans, A. H. A.; Laarhoven, W. H.

Book ID
120559392
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
751 KB
Volume
96
Category
Article
ISSN
0002-7863

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We report extended basis set SCF treatments of the recently synthesized first stable Al' compound ( AICsR,)4, R = CH3 experimentally, R-H in the calculations. For comparison we consider the series AIX, X=H, F, Cl, C5H,, and its tetramers. Bonding in the tetramers, showing an Al4 tetrahedron, is much