✦ LIBER ✦

Photodecomposition of ketene in the presence of a continuous electric field

✍ Scribed by J.C. Ferrero; G. Arbilla

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 518 KB
Volume: 187
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90445-f

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✦ Synopsis

The electric field effect on the UV decomposition of ketene was studied. The ratio of the main products [&H.,] / [C2Hs] which is proportional to [ CH2( 'A, ) ] / [CH2 ('B, ) ] 2 was measured as a function of pressure and as a function ofthe electric field strength in the range O-5 kV/cm. A significant dependence of this ratio on the electric field was observed up to a saturation value, These results can be explained in terms of the singlet-triplet collisional induced intersystem crossing.

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