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Photodecomposition of cis- and trans-2,4-dimethylcyclobutanones in the gas phase. Stereochemical inversion in the decarbonylation process and unimolecular lifetime of the hot ground state

✍ Scribed by Lee, Edward K. C.; Carless, Howard A. J.


Book ID
126294334
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
390 KB
Volume
92
Category
Article
ISSN
0002-7863

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Study of thermal decomposition of poly(v
✍ V. ChytrΓ½; B. Obereigner; D. Lim πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 English βš– 539 KB

The decompositions of the following poly(vinyl chloride) models were investigated in the gas phase: trans-l,3-dichloro-l-pentene (in the range 310-380Β°), trans-5-chloro-3-heptene (296-357Β°), cis-4-chloro-2-pentene (295-340 Β°) and racem, and meso 2,4-dichloropentane at 351 and 370 Β°. The decompositio