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Photocycloaddition reactions of 2-acylcyclohex-2-enones

โœ Scribed by Ferrer, Leticia Oliveira; Margaretha, Paul

Book ID
120154300
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
44 KB
Volume
5
Category
Article
ISSN
1359-7345

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## Abstract The newly synthesized 2โ€(alkโ€3โ€enโ€1โ€ynyl)cyclohexโ€2โ€enones **4** undergo photodimerization (chemoโ€ and regioโ€)selectively at the exocyclic C๏ฃพC bond to give diastereoisomeric mixtures of 1,2โ€dialkynylโ€1,2โ€dimethylcyclobutanes. On irradiation of **4** in the presence of 2โ€chloroacrylonitr