Photocycloaddition of Cyclohex-2-enones to Tetramethoxyethylene: Formation of 2,2,3,3-Tetramethoxy-1-oxaspiro[3.5]non-5-enes
✍ Scribed by Giuliano Cruciani; Hans-Jürgen Rathjen; Paul Margaretha
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- German
- Weight
- 233 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0018-019X
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## Abstract On irradiation, in the presence of 2,3‐dimethylbuta‐1,3‐diene, naphthalen‐2‐ones **1** are quantitatively and regioselectively converted to mixtures of diastereoisomeric cyclobutane adducts **3** and **4**, whereas, under these conditions, 3‐(alk‐1‐ynyl)cyclohex‐2‐enones **5** give only
## Abstract The newly synthesized 2‐(alk‐3‐en‐1‐ynyl)cyclohex‐2‐enones **4** undergo photodimerization (chemo‐ and regio‐)selectively at the exocyclic CC bond to give diastereoisomeric mixtures of 1,2‐dialkynyl‐1,2‐dimethylcyclobutanes. On irradiation of **4** in the presence of 2‐chloroacrylonitr
## Abstract The title cyclohexenone **1d** undergoes photodimerization selectively at the exocyclic CC bond to give a 1 : 1 mixture of 1,2‐dialkynyl‐1,2‐dimethylcyclobutanes **6** and **7**. On irradiation in the presence of 2,3‐dimethylbuta‐1,3‐diene, **1d** affords bicyclo[8.4.0]tetradeca‐1,2,3,
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v