𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photocyclization Reaction of some 2-Methyl-4-phenyl- Substituted Aldehyde Thiosemicarbazones. Mechanistic Aspects

✍ Scribed by Silvestre Buscemi; Michelangelo Gruttadauria


Book ID
104202495
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
110 KB
Volume
56
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis


Irradiation of 2-methyl-4-phenyl-substituted benzaldehyde thiosemicarbazones led with good yields to the corresponding D 2 -1,2,4-triazoline-5-thione derivatives through the formation of stable 1,2,4-triazolidine-5-thione intermediates. The relative quantum yields of photocyclization at 313 nm were analysed by means of the Hammett equation and r values determined. We interpreted the results in terms of the mechanism of photocyclization of 2-methyl-4-phenyl-substituted benzaldehyde thiosemicarbazones.


πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Photocyclization Re
✍ Silvestre Buscemi; Michelangelo Gruttadauria πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v