## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
β¦ LIBER β¦
Photocyclization Reaction of some 2-Methyl-4-phenyl- Substituted Aldehyde Thiosemicarbazones. Mechanistic Aspects
β Scribed by Silvestre Buscemi; Michelangelo Gruttadauria
- Book ID
- 104202495
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 110 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0040-4020
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β¦ Synopsis
Irradiation of 2-methyl-4-phenyl-substituted benzaldehyde thiosemicarbazones led with good yields to the corresponding D 2 -1,2,4-triazoline-5-thione derivatives through the formation of stable 1,2,4-triazolidine-5-thione intermediates. The relative quantum yields of photocyclization at 313 nm were analysed by means of the Hammett equation and r values determined. We interpreted the results in terms of the mechanism of photocyclization of 2-methyl-4-phenyl-substituted benzaldehyde thiosemicarbazones.
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