Photocrosslinkable copolyesters: Poly(alkylene terephthalate-co-1,4-phenylene bisacrylate)
✍ Scribed by Marian Vargas; David M. Collard; Charles L. Liotta; David A. Schiraldi
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 192 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
No coin nor oath required. For personal study only.
✦ Synopsis
1,4-Phenylene bis(acrylic acid) is a thermally stable diacid, which can be incorporated into polyesters. The phenylene bisacrylate structural units undergo rapid photochemical reaction in the solid state to form crosslinks. This constitutes a feasible approach to polyesters, which can be photochemically thermoset after fabrication as films and fibers.
📜 SIMILAR VOLUMES
The melting behavior of poly(ethylene terephthalate co-1,4-cyclohexylene dimethylene terephthalate) [PET/CT] random copolyesters has been studied. The basis of this analysis was the triple melting behavior of PET homopolymers, which is commonly observed after a period of isothermal crystallization f
## Abstract A set of amorphous poly[ethylene‐__co__‐(1,4‐cyclohexanedimethylene terephthalate)] (PECT) copolymers containing 25 and 30% of 1,4‐cyclohexane dimethylene (CHDM) units and small amounts of branching agent pentaerythritol (PER) is investigated. The level of long chain branching was estim