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Photochromism of diarylethenes having nitronyl nitroxides

✍ Scribed by Kenji Matsuda; Masahiro Irie *

Book ID
104210081
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
143 KB
Volume
41
Category
Article
ISSN
0040-4039

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Photochromism of Diarylethenes with Two
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Photochromic diarylethenes that have p-phenylene-substituted benzothiophene aryl groups with and without nitronyl nitroxide radicals at both ends of the molecules were synthesized. The absorption maxima of the closedring isomers showed a hypsochromic shift with the increase in the p-conjugated chain

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## Abstract Silsesquioxanes having 1‐(2‐methylbenzo[b]thien‐3‐yl)‐2‐[5‐(4‐butylphenyl)‐2,4‐dimethylthien‐3‐yl]perfluorocyclopentenes as the pendant groups were synthesized. Photochemical conversion from the open‐ring to the closed‐ring form of diarylethenes chemically bonded to polymers was by 15–2