Furo-Fused 2H-Chromenes: Synthesis and Photochromic Properties. -Two alternative approaches for the synthesis of furo-fused chromenes ( III) and (IV) starting from hydroxybenzofurans (I) are given. All the new chromenes exhibit photochromic behavior at room temperature. -(POZZO,
Photochromic Properties of New Benzoindene-Fused 2H-Chromenes
✍ Scribed by Cristina I. Martins; Paulo J. Coelho; Luis M. Carvalho; Ana M. F. Oliveira-Campos; André Samat; Robert Guglielmetti
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- German
- Weight
- 144 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The synthesis and the photochromic properties of new photochromic 6,7‐ and 7,8‐benzoindene annellated benzopyrans are described. When compared to parent indeno‐fused 2__H__‐chromenes (2__H__‐[1]benzopyrans), compounds 10 and 12 exhibit a significant bathochromic shift of maximum‐absorption wavelength, an increase in the colorability, and similar fading rates.
📜 SIMILAR VOLUMES
In the 2H-chromene series, complexation of the aromatic ring with chromium tricarbonyl, under thermal conditions, is totally regioselective even when aromatic substituents are introduced on the pyran ring. The complexation stabilizes the open form of these photochromic compounds and reduces the ther