## Abstract The (__E__)‐ and (__Z__)‐isomers of the 3,3,__n,n__‐tetramethyl‐2‐(methoxyimino)‐1‐cycloalkanones (__n__ = 5 to 7) (3a‐c) and their acyclic analogue (__Z__)‐4‐(methoxyimino)‐2,2,5,5‐tetramethyl‐3‐hexanone [(__Z__)‐4] have been irradiated at λ 254 nm in acetonitrile as solvent in order t
✦ LIBER ✦
Photochemistry of α-oxo oximes. Part 9. The γ-hydrogen abstraction in α-oxo oxime ethers
✍ Scribed by Theo S. V. Buys; Hans Cerfontain; Jan A. J. Geenevasen; Frank Stunnenberg
- Book ID
- 104588750
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 685 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0165-0513
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## Abstract Photochemical __E‐Z__ isomerization of 2‐(methoxyimino)‐1‐indanone (1) and its 7‐methyl derivative (2) was studied under conditions of direct irradiation (λ 350 and 300 nm) and triplet photosensitization. The decay ratios __k__~5~/__k__~6~ for triplet photosensitization and direct irrad
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