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Photochemistry of polyhaloarenes. 6. Fragmentation of polyfluoroarene radical anions

✍ Scribed by Freeman, Peter K.; Srinivasa, Ramanujan


Book ID
120863868
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
622 KB
Volume
52
Category
Article
ISSN
0022-3263

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ESR. and, in part, ENDOR. studies are reported on the radical anions of 5,5'and 6,6'-biazulenyl (1 and 2, resp.), as well as on their 1,1',3,3'-tetradeuterioderivatives (1-d4 and 2-d4). The reduction processes of 1 and 2 leading to these radical anions (1Q and 28) and the dianions (1" and 2e) have b