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Photochemistry of non-conjugated dienones: Irradiation of trans-α-ionone

✍ Scribed by A. van Wageningen; Th. J. de Boer

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
166 KB
Volume
89
Category
Article
ISSN
0165-0513

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✍ Cornelis P. Visser; Hans Cerfontain 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 359 KB

## Abstract The photochemical reactions of (__E__)‐α‐ionone (**1**) and its photoproducts have been re‐examined. Upon irradiation with λ 254 and 313 nm a sequence of photo‐reactions takes place: initially (__Z__)‐α‐ionone (**2**) is formed and subsequently (__E__)‐ and (__Z__)‐__retro__‐α‐ionone (*