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Photochemistry of N2O·H2O cpmplexes produced in supersonic jets

✍ Scribed by Hong Lae Kim; Masao Takayanagi; Ichiro Hanazaki

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
405 KB
Volume
222
Category
Article
ISSN
0009-2614

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✦ Synopsis

We have studied the 193 nm photodissociation of N20-H20 complexes produced in a supersonic jet resulting in the reactantpair reaction, N20*HZO+hv+20H+N,.

Measured internal energy, spin-orbit and n-doublet distributions in OH by laserinduced fluorescence suggest a reaction scheme much different from the corresponding bimolecular reaction, 0( 'D) + H,O+20H, observed in bulb experiments. The reaction should proceed slowly through the 0 ( 'D) +O( 3P2) curve crossing and a relatively long-lived reaction intermediate.

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