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Photochemistry of methyl diazoacetate in chloromethanes studied by CIDNP [chemically induced dynamic nuclear polarization]

✍ Scribed by Iwamura, Hiizu; Imahashi, Yuzo; Kushida, Katsuhiko


Book ID
126823203
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
357 KB
Volume
96
Category
Article
ISSN
0002-7863

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Olefin Isomerization via Radical-Ion Pai
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## Abstract Geometric isomerizations of olefins following photoinduced electron transfer (PET) are classified according to the relative energetic positions of the radical‐ion pairs and the reactant triplets. Each class exhibits characteristic CIDNP (chemically induced dynamic nuclear polarization)