Photochemistry of large ring 2-phenylcycloalkanones and 2,n-diphenylcycloalkanones
โ Scribed by Xuegong Lei; Charles Doubleday Jr.; Nicholas J. Turro
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 196 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Photolysis of the title compounds (n=10.11,12,15) yields mainly cyclophanes.
๐ SIMILAR VOLUMES
## The photochemistry of solid complexes of large ring 2-phenylcycloalkanones adsorbed in cyclodextrin cavities results in significant yields of enals as disproportionation products, at the expense of the pararearrangement, depending on both the ring size of the cyclanone and the cavity size of the
## Abstract Irradiation (ฮป = 254 nm) of __N__โ(4,4,6,6โtetramethylโ2โcyclohexenโ1โylidene)โ1,1,3,3โtetramethylโ2โcyclohexenโ1โylideneโ1,1,3,3โtetramethylbutylamine **(7d)**, which in turn is photodecomposed by light of the same wavelength, but at a four times slower rate than it is formed. The rate
The reaction COWM of biraakals, O=Cr-(CH&2-CfPh2. generated from Norrish type I reaction of 2,2-dtphenylcycloakanones with various ring sizes, IS switched from intramolecular disproportionahon (n=6.7) to acyl-phenyl recombination (r&J in methanol. Norrish type I (photochemical a-cleavage) reactions