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Photochemistry of Hemicyclone Diels-Alder Adducts of Substituted Benzoquinones

✍ Scribed by Coxon, JM ;Oconnell, MJ ;Steel, PJ


Book ID
121328334
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1986
Tongue
English
Weight
935 KB
Volume
39
Category
Article
ISSN
0004-9425

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We have recently embarked upon a study of the photochemistry of a variety of enonediene Diels-Alder adducts (2,3). For example we have found that irradiation of the 2,3-dimethylbutadiene-benzoquinone adduct I leads, very likely via an intramolecular allylic -B-hydrogen abstraction, to the products I