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Photochemistry of ethyl 4-substituted 2-cyano-1,2-dihydroquinoline-1-carboxylates (Reissert compounds): syntheses of cycloprop[b]indoles

✍ Scribed by Ikeda, Masazumi; Matsugashita, Saeko; Tabusa, Fujio; Tamura, Yasumitsu

Book ID
120611176
Publisher
Royal Society of Chemistry
Year
1977
Weight
710 KB
Volume
10
Category
Article
ISSN
1472-7781

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✍ Reinhard TroschΓΌtz; Annin Hoffmann πŸ“‚ Article πŸ“… 1997 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 830 KB

## Abstract The preparation of 3‐amino‐ and 3‐dialkylamino‐4‐cyanoazepino[3,4‐fc]indoles bearing substituents on the aromatic nucleus and N^10^ is outlined. Starting from suitable substituted ethyl 3‐formylindole‐2‐carboxy‐latcs 2, condensation with malononitrile (3) and subsequent sodium borohydri