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Photochemistry of epoxyquinones: photoinduced cycloaddition of 2,3-epoxy-1,4-naphthoquinones with olefins

✍ Scribed by Kazuhiro Maruyama; Seiichi Arakawa; Tetsuo Oysuki


Book ID
107858108
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
201 KB
Volume
16
Category
Article
ISSN
0040-4039

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+ 2) Cycloaddition / Zwitterion formation / Ketene aminal l,l-Bis(dimethylamino)-1,3-butadiene (1) as a strong donor diene = 0.03 V vs. SCE, 1st IP, = 6.94 eV) is treated with acrylonitrile, dimethyl dicyanofumarate, and tetracyanoethylene. Cycloaddition with acrylonitrile is slow and requires eleva