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Photochemistry of epoxides. the acetone sensitized rearrangement of 3,4-epoxyolefins

✍ Scribed by D.R. Paulson; G. Korngold; G. Jones

Book ID: 104236697
Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 183 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84731-6

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✦ Synopsis

We have recently initiated a general research program to study the photochemistry of epoxyolefins. The present paper describes our initial results on the photochemical rearrangement of the monoepoxides of conjugated dienes. Irradiation2 of acetone solutions of 3,4-epolcyolefins (.OBM) at 30001 results in the formation of S , y-unsaturated ketones. Several examples are shown in the Table. An interesting

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