Rearrangement reactions are ubiquitous and they can occur both in the ground state as well as in the excited state. [1] The photochemical properties of stilbene-type compounds are well-documented [2ยฑ4] and major reactions include cis ยฑ trans isomerization, exciplex reactions, addition, and oxidative
โฆ LIBER โฆ
Photochemistry of Dibenzoylethylene; A Novel Photochemical Rearrangement and Reduction
โ Scribed by Griffin, Gary W.; O'Connell, Edmond J.
- Book ID
- 127100340
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 248 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
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WHEN an ethanolic suspension of trans -1,2 -dibenzoylethylene (DBE) is treated with triethyl phosphite at ambient temperature, a deep green color forms. The DBE gradually dissolves and is replaced by a precipitate of meso-1, 2, 3, 4-tetrabenzoylbutane (Ia), m.p. 202-203', identified+ by acid-catalyz
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