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Photochemistry of Dibenzoylethylene; A Novel Photochemical Rearrangement and Reduction

โœ Scribed by Griffin, Gary W.; O'Connell, Edmond J.


Book ID
127100340
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
248 KB
Volume
84
Category
Article
ISSN
0002-7863

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WHEN an ethanolic suspension of trans -1,2 -dibenzoylethylene (DBE) is treated with triethyl phosphite at ambient temperature, a deep green color forms. The DBE gradually dissolves and is replaced by a precipitate of meso-1, 2, 3, 4-tetrabenzoylbutane (Ia), m.p. 202-203', identified+ by acid-catalyz