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Photochemistry of diaryl substituted 1,2-dithiolylium salts.

✍ Scribed by Carl Th. Pedersen; Christian Lohse


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
202 KB
Volume
13
Category
Article
ISSN
0040-4039

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Reactions of 3,5-Diaryl-1,2-dithiolium S
✍ Hartke, Klaus ;Kraska, Andreas ;Massa, Werner ;Molinier, Michel ;Wocadlo, Sigrid πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 913 KB

## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit