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Photochemistry of coordination compounds. 15. trans- and cis-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate

✍ Scribed by Pribush, Robert A.; Wright, Robin E.; Adamson, Arthur W.

Book ID: 126324007
Publisher: American Chemical Society
Year: 1977
Tongue: English
Weight: 958 KB
Volume: 99
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00450a016

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## Abstract The solvolysis of __cis__(chloro)(1‐amino‐propan‐2‐ol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propan‐2‐ol, __t__‐butanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first